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Comparing Different Analytical Techniques to Monitor Lubricating Grease Degradation

机译:比较不同的分析技术来监测润滑脂降解

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During lubricant operation temperature, pressure and load are well known as the main factors enhancing degradation. To monitor this degradation process in lubricating oils, the industry has defined specific test methods involving correct sampling techniques and analytical techniques to provide efficient information on the correct oil change interval. Moreover, modern oil-lubricated systems apply specific oil monitoring procedures as part of condition based maintenance practices to detect root cause failures and prevent equipment damage. Applying these condition monitoring practices on lubricating greases is much more complex as once these greases are put into service, it becomes rather difficult for end-users to perform on-site grease condition monitoring, and define the correct frequency for re-greasing bearings. This explains why industry relies for grease-lubricated systems procedures on time-based intervals (preventive maintenance). In this study, research was performed, using a grease based on mineral oil and lithium soap thickener. Additional research was performed on the polyurea type of grease, in order to define the possibilities of monitoring antioxidants in polyurea greases. The greases were oxidized to produce samples at different intervals in order to evaluate different techniques, more specifically: Acid Number (AN), LSV (linear sweep voltammetry - RULER) and FTIR on the grease and its corresponding oil, viscosity, ICP and DSC. Beside the maximum information that the selected analytical techniques should give on the grease condition, the program has also evaluated the minimum quantity of sample, minimum time and the cost of analysis. During the study, different technologies available on the matter have been compared, which allow the optimization of the frequency of grease changes. Below are shown the different techniques used and the results obtained.
机译:在润滑剂操作期间,压力和载荷是众所周知的主要因素,增强降解的主要因素。为了监测润滑油中的这种降解过程,该行业已经定义了涉及纠正采样技术和分析技术的特定测试方法,以提供有关正确的油变化间隔的有效信息。此外,现代油润滑系统将特定的石油监测程序应用于基于条件的维护实践的一部分,以检测根本原因故障并防止设备损坏。在将这些润滑脂投入使用后,应用这些条件监测实践在润滑脂中的润滑脂更复杂,最终用户对现场润滑装置监测变得相当困难,并为重新润滑轴承定义正确的频率。这解释了为什么工业依赖于基于时间的时间间隔的油脂润滑系统程序(预防性维护)。在这项研究中,使用基于矿物油和锂皂增稠剂的油脂进行研究。对聚脲类型的油脂进行了额外的研究,以确定在多脲润滑脂中监测抗氧化剂的可能性。将润滑脂氧化以以不同的间隔产生样品,以便评估不同的技术,更具体地:酸性数(AN),LSV(线性扫描伏安ramery-Ruler)和FTIR在润滑脂及其相应的油,粘度,ICP和DSC上。除了所选分析技术应给予润滑脂条件的最大信息旁边,该程序还评估了最小量的样品,最短时间和分析成本。在研究期间,比较了此事上可用的不同技术,这使得润滑脂频率变化的优化。下面示出了所用的不同技术和所获得的结果。

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