THE CHARACTERISATION OF MOLECULAR CESIUM BROMATE BY MATRIX ISOLATION I.R. SPECTROSCOPY

摘要

Vaporization of solid CsBrO_3 at 730 K results in the formation of molecular CsBrO_3, which is identified by matrix isolation i.r. spectroscopy as having a C3v structure involving tridentate coordination. The existence of this species may have a bearing on the atmospheric chemistry of bromine oxo-species.