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Nucleation Kinetics of Calcium Carbonate in Gas Field Brine Containing Methanol

机译:含甲醇的气田盐水中碳酸钙的成核动力学

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Calcium carbonate precipitation from gas-field brine under the influence of methanol was experimentally investigated in the present study. Precipitation in gas pipelines arises problems of scale formation, corrosion, and pressure drop. The experimental results of this study showed that the induction time for precipitation increased from 39 minutes for a brine solution containing 40 wt(percent) methanol to 53 minutes for a solution containing 60 wt(percent) methanol. A higher concentration of methanol resulted in more mass of precipitates and larger size particles. The produced precipitates of 5.33 g solid from one kg water in the absence of methanol rose to 5.92 g solid from one kg water in the presence of 60 wt(percent) methanol indicating an increase of 11percent. Methanol also revealed to be influential in the morphology of precipitates by gradually changing calcite to vaterite at higher concentrations of methanol. The results of this research may be used in the petroleum industry to predict the scale formation of calcium carbonate in the field brine of gas production processes.
机译:在本研究中实验研究了在甲醇的影响下的气田盐水中碳酸钙沉淀。气体管道中的沉淀出现了规模形成,腐蚀和压降的问题。本研究的实验结果表明,诱导时间沉淀39分钟增加到对于含有40重量(%)的甲醇至53分钟,含有60重量(%)的甲醇溶液中的盐水溶液洗涤。较高浓度的甲醇导致更多的沉淀物和较大尺寸的颗粒。在没有甲醇的情况下,在没有甲醇的情况下,从一kg水的产生沉淀物为5.92g固体,在60wt(百分比)甲醇存在下,甲醇的存在表示增加。在较高浓度的甲醇中,甲醇还显示出在沉淀物的形态中有影响力。该研究的结果可用于石油工业,以预测气体生产过程中盐水中碳酸钙的规模形成。

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