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Recovery of Gold by Solutions of Neutral Sulfurorganic Extractants in Liquid Carbon Dioxide

机译:通过液体二氧化碳中的中性硫磺萃取剂溶液回收金

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The most generally employed method for gold recovery from ores is cyanide technique by means of which more than 70% metal are produced. The technique is based on treatment of ores by aqueous solution of NaCN or other organic cyanides in the presence of oXy£en. The process proceeds in accordance with the following expression: 4Au + 8NaCN + 2H2O + O2 => 4NaAu(CN)2 + 4NaOH With allowance for cheapness of all reagents including water as solvent, the cyanide method has essential drawbacks - low selectivity of the process. Along with gold and silver the considerable amounts of copper, zinc, iron cobalt manganese other accompanying elements are recovered on treatment of initial ore. osses of noble metals due to separation of leached ore from process solutions; necessity for concentrating of process solutions; low process effectiveness on treatment of strong ores; high toxicity of cyanide compounds Non-cyanidable forms of gold in ores of different origin represent a metal covered by dense thin layer of iron hydroxide films and disseminations into rock-forming minerals Therefore, additional expenses are required for special protection measures, control over content of hazardous components and the environmental protection concerned with treatment of cyanide-containing waste. The trend universally adopted in industry and directed to more severe requirements imposed on the ecological safety increases production costs of enrichment facilities, adds to risk of penal sanctions and thus decreases profitability of ore tieatment by cyanide process. So, in the last ten years the investigations are underway on searching some new reagents as cyanide substituents and on developing the systems to leach noble metals from ores.
机译:最普遍采用的金回收来自矿石的金属是氰化物技术,通过该技术产生超过70%的金属。该技术基于在氧气存在下通过NaCN或其它有机氰化物的水溶液的处理。该过程按照以下表达进行:4AU + 8NACN + 2H2O + O 2 => 4naau(CN)2 + 4naOH,含有水作为溶​​剂的所有试剂的廉价性,氰化物方法具有基本的缺点 - 该过程的低选择性。随着黄金和银相当大量的铜,锌,铁钴锰其他伴随的元素在治疗初始矿石上被回收。由于浸出矿石从过程解决方案的分离,贵金属的OSSES;集中工艺解决方案的必要性;对强矿石治疗的低工艺效果;氰化物化合物的高毒性不同原点中的矿石中的非氰化物形式代表了由致密薄层氢氧化铁薄膜覆盖的金属,并在岩石成形矿物中散布,特殊保护措施需要额外的费用,控制含量危险组件与含氰废料治疗的危险组件和环保。行业普遍采用的趋势和针对生态安全施加更严重的要求提高了富集设施的生产成本,增加了刑事制裁的风险,从而降低了氰化物过程的矿石盈利能力。因此,在过去十年中,调查正在寻求将一些新试剂作为氰化物取代基以及从矿石中浸出贵金属的系统。

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