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A New Class of High Temperature and Corrosion Resistant Nickel-Based Open-Cell Foams

机译:一类新的高温和耐腐蚀镍的开放式开放式电池泡沫

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A number of nickel-based (e.g. Inconel) and iron-based (e.g. Incoloy or Fecralloy) alloys have been successfully developed for applications at high service temperatures and in corrosive environments. Applications such as diesel particulate filters, heat exchangers, and catalyst supports require open-cell porous structures with tailored and uniform material and structural properties, a requirement which can be met by high temperature and corrosion resistant metallic alloy foams prepared with compositions similar to those mentioned above. A new technology that transforms pure nickel foam into an alloy foam, and which has now reached the pilot plant production stage, will be introduced. This technique starts from commercially-available nickel foam, which is uniformly coated with a pre-alloyed powder using standard powder metallurgical methods, and subsequently transformed into the desired alloy throughout the strut cross-section in a relatively short time with a carefully controlled heat treatment that utilizes transient liquidphase sintering. This process allows for the preparation of a wide variety of foam compositions and structural features, which is important for tailoring material properties to a specific application. As the physical dimensions of the final alloy foam structure are similar to those of the starting nickel foam, which is available in different pore sizes, it is possible to produce alloy foams over a wide range of pore sizes (i.e. from approx 300-mum to over 2000-mum) by this method. In this way, the foam surface, transport, and filtration properties can be widely adapted to the respective applications. An overview of the most promising alloy foams will be given, with respect to sintering behaviour, mechanical properties, and corrosion testing. A specific focus will be to demonstrate the potential of Fe-Ni-Cr-Al foams for use in high temperature applications. Another important aspect that will be covered is the manufacturability of the foams; different product shapes will be shown and their manufacturing will be explained. The discussion of the current applications for these alloy foams will focus on diesel soot filtration with respect to the filtration properties (e.g. back pressure, efficiency, filter design, etc.) of the alloy foams.
机译:已经成功开发了许多基于镍(例如Inconel)和基于铁的基于铁(例如Incoloy或Fecralloy)合金,用于高服务温度和腐蚀性环境中的应用。应用,例如柴油机微粒过滤器,热交换器,和催化剂载体需要具有定制和均匀的材料和结构特性的开孔的多孔结构,这可以通过在高温和耐腐蚀的金属合金来满足具有类似于那些提到的组合物制备的泡沫的要求以上。将介绍一项将纯镍泡沫转化为合金泡沫的新技术,现在将介绍该技术,现在已经达到了试验厂生产阶段。该技术从市售的镍泡沫开始,其使用标准粉末冶金方法均匀地涂覆有预合金粉末,随后在相对短的时间内在较短的横截面中转化成所需的合金,仔细控制的热处理利用瞬时液相烧结。该方法允许制备各种泡沫组合物和结构特征,这对于定制材料特性至特定应用是重要的。由于最终合金泡沫结构的物理尺寸类似于可在不同孔径的起始镍泡沫的物理尺寸,因此可以在宽范围内生产合金泡沫(即,从大约300毫米到通过这种方法超过2000毫米。以这种方式,泡沫表面,运输和过滤性能可以广泛适用于各自的应用。关于烧结行为,机械性能和腐蚀测试,将给出最有前途合金泡沫的概述。特定的重点是展示Fe-Ni-Cr-Al泡沫用于高温应用的潜力。将涵盖的另一个重要方面是泡沫的可制造性;将显示不同的产品形状,并将解释其制造。对这些合金泡沫的目前应用的讨论将专注于合金泡沫的过滤性能(例如背压,效率,过滤器设计等)的柴油烟灰过滤。

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