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THE CHEMICAL WIZARDRY OF ISOPRENOID METABOLISM IN PLANTS

机译:植物中异戊二烯代谢的化学巫术

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Mention terpenes, or more properly isoprenoids, to a biologist and they are likely to conjure up mental images of chemical structures with a striking similarity to hexa-methyl chicken wire. Mention the same to a chemist and they are likely to imagine swirling electrons and carbocations within the complexities of the chicken wire. Yet, everyone is familiar with terpenes. These are the compounds that give many of our foods wonderful aromas and tastes, and the fresh scents to many of our household cleaning products. They include pinenes (pine scent) and nootkatone (distinctive grapefruit taste) (Fig. 10.1). These are some of the obvious ways we have taken advantage of these compounds. Biologically, they are immensely important compounds in plants, fungi, bacteria, and insects, which provide unique means for these organisms to sense and interact with their environment, as well as to serve as internal signals coordinating developmental programs. Two recent examples from the literature help to illustrate this point.
机译:提及Terpenes,或更适当的异戊二烯,对生物学家,他们可能会唤起与Hexa-甲基鸡丝的相似性引起的化学结构的心理形象。提到化学家的同一个,它们可能会想象在鸡丝的复杂性内旋流电子和碳酸。然而,每个人都熟悉Terpenes。这些是给我们许多食物美妙的香气和口味的化合物,以及许多家庭清洁产品的新鲜气味。它们包括Pinenes(松香)和耳蛋黄(独特的葡萄柚味)(图10.1)。这些是我们利用这些化合物的一些明显方式。在生物学上,它们在植物,真菌,细菌和昆虫中是非常重要的化合物,这为这些生物提供了独特的手段,以便与其环境感觉和相互作用,以及作为内部信号协调发展计划。来自文献的两个例子有助于说明这一点。

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