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STUDY OF THE SILICON CARBIDE MATRIX ELABORATION BY FILM BOILING PROCESS

机译:胶片沸腾工艺碳化硅基质阐述的研究

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Film-boiling technique is a Ceramic Matrix Composites fabrication process, especially studied for the densification of carbon based composites. The densification starts from the porous preform, heated at high temperature in a liquid precursor which becomes gaseous in contact with hot surfaces. The cracking of the vapours results in a solid deposit constituting the matrix of the final composite. The main advantage of the film-boiling technique is its high densification rate: up to several hundreds of μm/h depending on the experimental set up (versus ~2μm/h in CVI). To get a better insight on this process, laboratory scale equipment with an internal resistive heating was developed. In this work, carbon preforms are densified by silicon carbide (SiC) matrices. Two SiC precursors are used: the methyltrichlorosilane (MTS) and the CVD4000. The samples characterizations show that the quality of the matrix (density, homogeneity, crystalline phase…) and the densification rate depend on several experimental settings (type of precursor, densification temperature…).
机译:薄膜沸腾技术是一种陶瓷基复合材料制造工艺,特别是研究了碳基复合材料的致密化。致密化从多孔预制件开始,在高温下在液体前体中加热,其变得与热表面接触的气态。蒸汽的开裂导致构成最终复合材料基质的固体沉积物。薄膜沸腾技术的主要优点是其高致密化速率:根据实验组(在CVI中为2μm/ h),高达数百μm/ h)。为了更好地了解这一过程,开发了具有内部电阻加热的实验室规模设备。在这项工作中,通过碳化硅(SiC)基质致密化碳预制件。使用两个SiC前体:甲基三氯硅烷(MTS)和CVD4000。将样品表征表明,所述基质(密度,均匀性,结晶相...)和致密化速度的质量依赖于几种实验设置(类型的前体,致密化温度...)。

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