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Cell Structure of Detonations With Four-Step Chain-Branching Kinetics

机译:四步链分支动力学爆炸细胞结构

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We use a Weighed Essentially Non-Oscillatory (WENO)scheme to perform very long-time two dimensional numerical simulations of detonation waves with a four-step reaction model.This model consists of a chain-initiation step and a chain-branching step,both temperature-dependent with Arrhenius kinetics,followed by two pressure-dependent termination steps.A chain-branching cross-over temperature (T_B)is introduced and its effect on the explosion limits,steady structure and detonation cellular structure are discussed.Increasing the chain-branching temperature decreases the chain-branching rate,thus increases the ratio of the initiation length to the length of the recombination zone,which leads to more unstable detonations according to linear stability analysis.As T_B increases,the ratio cell length over width increases and the cell sizes also increases.Chain-branching kinetics also results in distinctive keystone figures,observed in the instantaneous results.The keystone figures are bounded by the shear layers that emanate from the triple points across which a discontinuity in reactivity occurs,and,behind Mach stems,by the layer where chain-branching occurs.
机译:我们使用权称重基本上非振荡(Weno)方案来执行具有四步反应模型的爆轰波的非常长时间二维数值模拟。该模型由链接步骤和链分支步骤组成温度依赖于Arrhenius动力学,然后介绍了两个压力依赖性终端步骤。讨论了链支链交叉温度(T_B),并讨论了对爆炸限制,稳定结构和爆炸蜂窝结构的影响。征收链 - 分支温度降低了链分支速率,从而提高了起始长度与重组区长度的比率,这导致根据线性稳定性分析的更不稳定的爆炸。如T_B增加,比率细胞长度随着宽度的增加而增加细胞尺寸也增加。分支动力学也导致在瞬时结果中观察到的特殊基石数字。梯形数字是有界B y从其中发生反应性中的间隙的三重点散发出来的剪切层,并且通过链分支的层后面,在马赫茎后面的情况下。

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