Hydrogen absorption-desorption characteristics of Ti_(0.22+X)Cr_(0.23+1.5X)V_(0.5-2.5X)(0≤X≤0.12) alloys

摘要

The hydrogen absorption-desorption characteristics of Ti_(0.22+X)Cr_(0.23+1.5X)V_(0.5-2.5X) (X=0, 0.04, 0.08, 0.10, 0.12) BCC alloys have been investigated at 303 K. The compositions of alloys were chosen for alloys to have equal lattice parameters of about 3.03 A by linear combination of each element. The alloys of about 20g each were arc-melted into button shaped ingots under argon atmosphere and re-melted five times to improve their homogeneities. The XRD analysis showed that all of the samples prepared had BCC single phases and their lattice parameters were nearly the same regardless of their chemical compositions. The P-C isotherms of the alloys revealed that the hydrogen storage capacities of the alloys exceeded 3 mass% owing to the control of the lattice parameters and only the second plateau was reversible at room temperature. The reversible structural transition from FCC to BCC occurred with dehydrogenation of the second plateau. The hydrogen unreleased even at considerably low pressure corresponds to the BCC hydride and needs thermal activation energy for desorption. The hydrogen absorption rate of the Ti_(0.32)Cr_(0.43)V_(0.25) alloy was considerably fast and more than 95% of the hydrogen was absorbed within the first 10 minutes.