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The Exothermic Behavior of Intermetallic Reactions in the Assimilation of Manganese Additions in Liquid Aluminum

机译:金属间反应在液体铝中锰添加中的金属间反应的放热行为

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The exothermic behavior of the intermetallic reactions inside an Al-Mn metallic powder compact and its assimilation fundamentals in molten aluminum were examined. In this study cylindrical compacts were manufactured and tested. The experimental work lvolved simultaneous temperature measurements of three thermocouples as well as detection of the apparent weight of the cylindrical specimen during its assimilation in quid aluminum. The details of the intermetallic reactions prior to the compact complete disintegration were investigated by microscopically studying the morphology and local composition in a partially reacted compact. The variation of manganese concentration in the melt was determined by chemically analyzing the samples taken from the molten aluminum at specific time intervals. The exothermic reaction increases the compact's temperature above that of the liquid aluminum. In tandem with this exothermic reaction, the compact is suffering a swelling action. This swelling action disintegrates the cylindrical specimen, which is assimilated into the liquid aluminum. The intermetallic reactions proceed in a stepwise manner. Both the bath temperature and the compact composition impact on the exothermicity of the intermetallic reactions. However, when the amount of Mn in the compact is greater than 75-wt percent, the maximum centerline temperature rise is slightly reduced as Mn amount increases.
机译:检查了Al-Mn金属粉末压块内金属间反应的放热行为及其在熔融铝中的其同化基础。在本研究中,圆柱形压块制造和测试。实验工作达到三个热电偶的同时温度测量,以及在桥铝中同化过程中检测圆柱形样品的表观重量。通过在部分反应的紧凑型中进行微观研究形态学和局部组合物来研究在紧凑完全崩解之前的金属间反应的细节。通过在特定时间间隔的特定时间间隔分析从熔融铝所取出的样品来确定熔体中锰浓度的变化。放热反应增加了高于液体铝的温度。串联伴有这种放热反应,紧凑型患有溶胀作用。这种膨胀作用崩解了圆柱形样品,其被同化在液体铝中。金属间反应以逐步的方式进行。浴温和紧凑的成分对金属间反应的放热产生影响。然而,当压块中的Mn的量大于75wt%时,随着Mn的量增加,最大中心线温度升高略微减少。

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