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Investigation of Epoxy Matrix Resistance Against the Low Earth Orbit Environment by Adding MWCNT and Nano-Silica

机译:通过添加MWCNT和纳米二氧化硅对低地轨道环境对抗大地轨道环境的环氧基质抗性研究

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摘要

Although composites have high specific strength and low coefficient of thermal expansion, the various hazards of the Low Earth Orbit(LEO) environment causes damage mostly on the surface of polymer matrix composites, creating microcracks, bringing about the degradation of mechanical properties, and resulting in dimensional changes. Generally, epoxy matrix is commonly used for composites but epoxy material does not display sufficient resistance against the attack of atomic oxygen and extreme thermal cycling. Thus, nano-fillers have been used to reinforce the epoxy matrix. Therefore, in this study, the resistance of multi-walled carbon nanotube(MWCNT) and nano-silica reinforced epoxy matrix was evaluated under 20 hours of simulated LEO environment involving 10~(-4)torr high vacuum, 200nm UV radiation, 14 thermal cycles ranging from-70~100°C, and AO fluence of 9.15x 10~(14)atoms/cm~2s. The mass loss of the specimens after aging under the simulated LEO environment was measured and the resistance was differentiated by analyzing the degree of variation of measured tensile properties according to ASTM D638. Moreover, in order to minimize agglomeration, a 3-roll mill equipment was used to evenly disperse the nano-filler within the matrix. The addition of nano-fillers reduced the surface damage from AO exposure to some extent, the material mass loss, and the degree of tensile properties reduction.
机译:尽管复合材料具有高比强度和低热膨胀系数,但低地轨道(LEO)环境的各种危害主要导致聚合物基质复合材料表面的损伤,从而产生微裂纹,从而产生机械性能的降解,并导致尺寸变化。通常,环氧基质通常用于复合材料,但环氧树脂物质不会对原子氧和极端热循环的攻击显示足够的抗性。因此,已使用纳米填料来加强环氧基质。因此,在该研究中,在模拟Leo环境的20小时内评价多壁碳纳米管(MWCNT)和纳米二氧化硅增强环氧基质的抗性涉及10〜(4)托的高真空,200nm紫外线辐射,14个热量循环范围为-70〜100°C,AO流量为9.15×10〜(14)原子/ cm〜2s。测量了在模拟Leo环境下老化后试样的质量损失,并且通过分析根据ASTM D638的测量拉伸性能的变化程度来区分电阻。此外,为了使聚集最小化,使用3辊轧机设备均匀地将纳米填料均匀地分散在基质内。添加纳米填料在某种程度上从AO暴露的表面损伤降低了表面损伤,材料质量损失和拉伸性能的降低程度。

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