Phosphines with Tetraethylene Glycol Chains Arranged at the Periphery: The Efficient Ligand in the Suzuki-Miyaura Coupling Reaction

摘要

As for homogeneous transition metal catalysts, modification of catalysts within a close proximity of a metal center (within a few angstroms) is a conventional way to develop efficient catalysts for various reactions. Meanwhile, catalytic environment can be expanded to a nanosize, and this unique environment has added new prospects to homogeneous catalysis.