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Performance investigation of low-toxic organic corrosion inhibitors in amine treating unit

机译:胺处理单位低毒有机腐蚀剂的性能调查

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Amine treating unit is constantly subject to severe corrosion problems leading to extra expenditure and operational limitations. Heavy-metal vanadium compounds are extensively used as corrosion inhibitors to suppress the severe corrosion to an acceptable level. In recent years, the fact that these vanadium compounds are inherently toxic and can potentially pose adverse impacts on the human health and the environment has brought about environmental awareness that causes their uses costly due to the difficulty in waste disposal. To respond to the environmental concern and reduce cost of waste disposal as well as prepare for more stringent regulations for chemical uses, the development of low-toxic corrosion inhibitors is necessary. This work therefore focuses on an investigation of inhibition performance of a number of organic and inorganic compounds that have relatively low toxicity in comparison with conventional inhibitors. The performance evaluation was carried out through corrosion experiments using carbon steel specimens. The experiments were done in 3 and 5 kmol/m~3 monoethanolamine (MEA) solution saturated with CO_2 at 80 deg C. It was found that several tested compounds have potential to be effective low-toxic corrosion inhibitors. The promising compounds provide reasonable and in some cases comparable protection performance to the conventional inhibitor.
机译:胺治疗单位不断受到严重的腐蚀问题,导致额外支出和运营限制。重金属钒化合物广泛用作腐蚀抑制剂,以抑制对可接受的水平的严重腐蚀。近年来,这些钒化合物本身有毒的事实,可能会对人类健康产生不利影响,环境引起了环境意识,导致其昂贵的废物处理难度昂贵。为了应对环境问题并降低废物处理的成本,并为化学用途的更严格规定做好准备,则需要开发低毒腐蚀抑制剂。因此,该工作侧重于与常规抑制剂相比具有相对低毒性的许多有机和无机化合物的抑制性能的研究。通过使用碳钢标本的腐蚀实验进行性能评估。将实验在3例和5例kmol / m〜3单乙醇胺(MEA)溶液中进行,饱和Co_2,在80℃下饱和。发现几种测试化合物具有有效的低毒腐蚀抑制剂。有希望的化合物提供合理的,并且在某些情况下为常规抑制剂的保护性能相当。

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