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A Simple Model to Predict Nonlinear Viscoelasticity and Shear Banding Flow of Wormlike Micellar Solutions

机译:一种简单的模型,可预测蜗杆胶束溶液的非线性粘弹性和剪切条流量

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A model consisting of the codeformational Maxwell constitutive equation coupled to a kinetic equation for breaking and re-formation of micelles is presented to reproduce most of the nonlinear viscoelastic properties of wormlike micelles. This simple model is also able to predict shear banding in steady shear and pipe flows as well as the long transients and oscillations that accompany this phenomenon. Even though the model requires six parameters, all of them can be evaluated from single and independent rheological experiments, and then they can be used to predict other flow situations. The predictions of our model are compared with experimental data for aqueous micellar solutions of cetyltrimethylammonium tosilate (CTAT).
机译:提出了一种由耦合到用于动力学方程的代码麦克斯韦尔本构方程组成的模型,用于再形成胶束的动力学方程,以再现蠕虫状胶束的大部分非线性粘弹性性质。这种简单的模型还能够在稳定剪切和管道流中预测剪切条带以及伴随这种现象的长瞬态和振荡。即使模型需要六个参数,所有这些都可以从单一和独立流变实验评估,然后它们可用于预测其他流动情况。将模型的预测与西甲基三甲基甘露钒(CTAT)的胶束溶液的实验数据进行了比较。

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