Spouted bed electrowinning in the recovery of zinc from scrap galvanized steel

摘要

There is a growing need to process galvanized steel scrap from automobiles, etc., in order to remove the zinc coating that otherwise causes problems in remelting of the scrap in electric arc furnaces. One approach that has moved to the pilot plant stage is that of Metal Recovery Technologies, Inc., of East Chicago (MRI). That company leaches the zinc from the scrap with a sodium hydroxide solution. The leached and washed scrap can then be returned to the steel industry. What is left is a sodiumhydroxide/zincate solution which must be processed to recover the zinc and the NaOH. Presently, this is done by MRI using electrodeposition on planar electrodes at moderate current density and the resulting zinc is in the form of fine powder which is hard to process into, say, zinc for galvanizing. MRI has supported an investigation of a novel electrode, the spouted bed electrode (SBE), for zinc electrodeposition. I laboratory cells, zinc particles with low porosity have been grown up to 3mm in size.Microanalysis of the deposited zinc showed low level of impurities. DC energy consumption values were usually in the range of 2-2.5 kWh/kg which is well below the energy consumption of the existing cells (and of present-day cells for electrowinning fromacid sulfate electrolytes). These results were achieved at current densities (few thousand A/m{sup}2) that are much higher than possible with conventional electrodes. Discussion is provided of the scale-up of the cell to a commercial scale.