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MIXED-GAS ADSORPTION ON HETEROGENEOUS SUBSTRATES IN THE PRESENCE OF LATERAL AD-AD INTERACTIONS

机译:在横向Ad-Ad相互作用存在下在异质基材上的混合气体吸附

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摘要

Adsorption of binary gas mixtures in the presence of ad-ad interactions is studied through grand canonical Monte Carlo simulation in the framework of the lattice-gas model. The disordered surface has been characterized by patches of shallow and deep sites, arranged in a chessboard-like topography. The adsorption process is monitored through partial and total isotherms, and differential heats of adsorption. Interesting behaviors have been observed depending on ad-ad interactions and energetic disorder.
机译:通过在格子气体模型的框架内通过大规范蒙特卡罗模拟研究了在AD-AD相互作用存在下的二元气体混合物。无序表面的特征在于浅层和深部位的斑块,布置在棋盘上的棋枰的地形中。通过部分和总等温线监测吸附过程,以及吸附的差异热量。根据AD-AD相互作用和能量疾病,已经观察到有趣的行为。

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