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Neptunium(V) Sorption by oc-FeOOH and γ-Fe{sub}2O{sub}3

机译:OC-FeOOH和γ-Fe {Sub} 2O {Sub} 3的Neptunium(V)吸附

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摘要

The mechanisms and kinetics of Np(V) sorption on well-characterized goethite (α-FeOOH) and magemite 3) were studied in batch experiments. Neptunium redox speciation on the mineral surface was studied using a solvent extraction technique and X-ray Photoelectron Spectroscopy (XPS). The distribution of Np(V) was analyzed using FITEQL software, and surface complexation reactions equilibrium constants were determined.
机译:在分批实验中研究了NP(v)吸附在良好表征的甲酸盐(α-FeO​​OH)和Magemite 3中的机制和动力学。使用溶剂萃取技术和X射线光电子谱(XPS)研究了矿物表面上的Neptunium氧化还原物质。使用FITEQL软件分析NP(V)的分布,测定表面络合反应平衡常数。

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