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Local Structure and Vibrational Properties of α'-Pu Martensite and Ga-Stabilized δ-Pu

机译:α-PU马氏体和GA稳定δ-PU的局部结构和振动性能

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Small additions of Ga can stabilize the fcc δ phase in Pu down to room temperature. Upon further cooling of Ga-doped Pu, a diffusionless martensitic partial transformation of the alloy occurs. In the transformed regions, the δ structure, in which Ga atoms are soluble and stable, changes to the monoclinic α structure, in which Ga atoms are insoluble but effectively trapped because of the very slow diffusion rates of Ga in the α matrix. This metastable phase consisting of Ga dopant atoms trapped within a monoclinic α-Pu matrix is termed the α' phase.
机译:GA的少量添加可以将PU的FCCδ相稳定到室温下降至室温。在进一步冷却Ga掺杂PU时,发生合金的扩散不含马氏体的分割。在变换区域中,Ga原子是可溶性和稳定的δ结构,对单斜α结构变化,其中Ga原子是不溶性而是有效地捕获,因为α基质中的Ga的非常慢的扩散速率。由捕获在单斜奈α-PU基质内的Ga掺杂剂原子组成的该亚稳态是称为α'相的。

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