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QUALIFICATION AND USE OF 13Cr TUBING IN BRAZILIAN OIL WELLS

机译:巴西油井13%Cr管的资格和使用

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The exploitation of oil and gas in Brazil offshore fields requires constant technical improvements. Deeper wells, slightly sour environments and CO_2 partial pressures ranging from 80 psia to 150 psia lead to the use Corrosion Resistant Alloys as an alternative to carbon steels due to the relatively high corrosivity of the Brazilian fields. The manufacturing of a 13%Cr tubing in Brazil was considered. In order to prove the capability of this manufactured tubing, a qualification program was carried out. This qualification program was made in a cooperative work and it is described in this paper. Three main aspects were considered and are presented: the manufacturing process, the quality evaluation and product qualification and finally definition of the conditions on which the material could be used. One of the main requirements of the manufacturing process is its reproducibility. Reproducibility is affected by the quality of the raw material and the process variables that control the manufacturing process. The quality of the tubing is then assured by a number of tests that evaluate its performance. The tests set by this qualifying program involved mechanical properties and corrosion tests. Mechanical properties were evaluated by tension, impact (at 0 and -60°C) and hardness. Corrosion tests included autoclave corrosion tests as well as SSC susceptibility. Those testes were conducted in H_2S and CO_2 environments that simulated actual production environments. For the qualifying program four different runs of 13Cr tubing were tested. General corrosion and also susceptibility to localized corrosion (weight loss and crevice) were evaluated at 80°C, 100% CO_2 in chloride containing media. SSC tests were performed in up to 95% of the specified yield strength, in various sets of pH, H_2S and CO_2 partial pressures, NaCl concentrations and temperatures. Results clearly showed the adequacy of the material to be used and also the capability of the mill plant to keep the quality of the manufactured products.
机译:巴西石油和天然气的开采近海场需要不断的技术改进。由于巴西领域的腐蚀性相对较高,更深从80psia至150psia的井中的井,略微酸性环境和CO_2部分压力导致使用耐腐蚀合金作为碳钢的替代方法。考虑了巴西13%Cr管的制造。为了证明该制造管的能力,进行了资格化计划。该资格计划是在合作工作中进行的,本文介绍了。考虑了三个主要方面并提出:制造过程,质量评估和产品资格,最终定义了材料可以使用的条件。制造过程的主要要求之一是其重现性。重现性受原料质量的影响和控制制造过程的过程变量的影响。然后通过评估其性能的许多测试来确保管道的质量。该资格化计划设定的测试涉及机械性能和腐蚀测试。通过张力,冲击(0和-60℃)和硬度来评估机械性能。腐蚀试验包括高压灭菌试验以及SSC易感性。这些睾丸是在模拟实际生产环境的H_2S和CO_2环境中进行的。对于合格程序,测试了四种不同的13Cr管道运行。在含氯化物培养基中的80℃,100%CO_2,在含氯化物中的100%CO_2评估一般腐蚀和对局部腐蚀(重量损失和缝隙)的敏感性。在各种pH值,H_2S和CO_2部分压力,NaCl浓度和温度中,SSC测试在最高可达95%的特定屈服强度的屈服强度进行。结果清楚地表明,采用材料的充分性以及轧机厂的能力,以保持制造产品的质量。

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