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Smart Autoclave Processing of Thermoset Resin Matrix Composites Based on Temperature and Internal Strain Monitoring

机译:热固性树脂基质复合材料的智能高压灭菌基于温度和内部应变监测

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Cure cycle optimization and process control for autoclave cure of thermoset resin matrix composites based on temperature and internal strain monitoring was studied. Cure of thermoset resin is usually exothermic reaction, which causes temperature increase of composites during cure. Slowing down the temperature ramp rate is effective in lowering the peak temperature. However, the slower the ramp rate is, the longer the cure time becomes. Therefore, it is desirable to control the ramp rate in order to depress the peak temperature with prolongation of cure time minimized. Besides that, precise determination of cure completion is also required in order to minimize cure time. The procedure for smart processing described above was developed and tried on laminate of carbon fiber / epoxy resin prepreg. In this procedure, temperature ramp rate is controlled so that the peak temperature predicted by Springer's thermochemical model is kept below allowable value. Cure completion is determined by cure rate equation and internal strain monitoring with embedded EFPI optical fiber sensors. The internal strain is correlated with specific volume change of the matrix resin caused by cure shrinkage and thermal expansion/contraction. The authors found that the cure shrinkage terminates at certain degree of cure, and EFPI sensors can detect this point. Although the degree of cure can be calculated by integrating the cure rate equation along temperature history, errors may be accumulated. Therefore, the degree of cure is corrected and integration of cure rate equation is restarted at the cure shrinkage termination point detected by EFPI sensors. Thus, cure completion is determined precisely. This smart autoclave processing procedure was able to depress the peak temperature and determine the end of cure.
机译:研究了基于温度和内部应变监测的热固性树脂基质复合材料的高压釜固化的固化循环优化和过程控制。热固性树脂的固化通常是放热反应,这导致固化过程中复合材料的温度升高。减慢温度斜坡率在降低峰值温度方面是有效的。然而,斜坡率较慢,固化时间越长。因此,希望控制斜坡率以使峰值温度延长最小化固化时间。除此之外,还需要精确测定治疗完成,以最大限度地减少治疗时间。上述智能处理的程序开发并尝试在碳纤维/环氧树脂预浸料坯的层压板上。在该过程中,控制温度斜坡速率,使得弹簧仪的热化学模型预测的峰值温度保持低于允许的值。用嵌入式EFPI光纤传感器固化速率方程和内部应变监测来确定治愈完成。内应变与由固化收缩和热膨胀/收缩引起的基质树脂的比体积变化相关。作者发现,固化收缩在一定程度的固化中终止,EFPI传感器可以检测到这一点。尽管可以通过沿着温度历史积分固化速率方程来计算固化程度,但是可以累积误差。因此,校正固化程度并在EFPI传感器检测到的固化收缩终止点处重新开始固化率方程的整合。因此,确切地确定固化完成。这种智能高压灭菌处理程序能够按下峰值温度并确定固化的结束。

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