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Investigation of Unburned Carbon on the Structure of Residual Ash

机译:对残余灰分结构的未燃碳调查

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The technical viability of a high-temperature gas clean-up system is essential for many of the new concepts in power plant design. A barrier-type filter now appears as the most appropriate solution to the problem. The most common type of barrier filter is the candle filter. The present problems with candle filters involve (1) the survivability of the filter in a harsh environment and (2) the removal of the ash deposits from the filter surface. This paper is concerned only with the latter problem. Ideally, the ash from the high-temperature dusty gas builds up on the outer surface of the candle filter. At either a prescribed time interval, or a prescribed pressure drop across the filter system, high-pressure gas is used for back-flushing the ash off the filter surface. This process is referred to as surface regeneration. At present, the surface regeneration process is not as effective as desired. Only the outer portion of the ash layer, referred to as the soft ash, is removed during surface regeneration. An inner layer of ash, the residual ash, survives the cleaning process. The residual ash layer appears to grow with time and may eventually contribute to the bridging between the candle filters. The growth and persistence of the residual ash may be noted on the performance history curves in [1], as illustrated in Figure 1. The basic goal of the filter system is to reduce the concentration of solids in the gas stream to an acceptable level with a minimum pressure drop. Many of the newer designs involving barrier filters are described in [2]. The cause(s) for the strong, stubborn, residual ash deposit has not yet been established. The two mechanisms that may account for the residual ash formation are: 1) the cohesive force(s) between the particles within the ash layer and 2) sintering [2]. Residual ash may form at low temperatures as well as high temperatures; consequently, sintering may only be significant at high temperatures. However, candle filters are intended to operate at high temperatures and the potential for sintering to occur must be considered. This study considers the problem of unburned carbon entering the ash layer on a candle filter. This unburned carbon may be due to incomplete combustion or system upsets. During surface regeneration, if air is used, a sufficient amount of oxygen will be present for combustion to occur in the ash layer. The heat generated during surface regeneration may then lead to sintering in the ash layer. Reference [2] describes occasional combustion on filters in a solid, smokeless fuel plant in England. These filtering systems were operating in the range of 200-300°C. Several of the filter fires lead to filter failures. The surface regeneration process was not performing properly and this was attributed to the pulse jet valves malfunctioning. Thermal stresses generated by the combustion of unburned carbon in the ash deposit on filters has been investigated [3]. Their research described the carbon concentration in four ash samples taken from an operating PFBC unit. This experimental study showed that when the carbon content was 16% (by weight) the change in filter surface temperature may reach 5000C. The resulting temperature rise was sufficient to predict filter failure due to thermal stresses.
机译:高温气体清理系统的技术可行性对于电厂设计中的许多新概念至关重要。屏障型过滤器现在显示为问题最合适的解决方案。最常见的屏障过滤器是蜡烛过滤器。蜡烛过滤器存在的问题涉及(1)滤波器在恶劣环境中的存活性,(2)从过滤器表面移除灰分沉积物。本文仅关注后一种问题。理想情况下,来自高温粉尘气体的灰烬在蜡烛过滤器的外表面上积聚。在规定的时间间隔或过滤系统上的规定压降,高压气体用于从过滤器表面上擦除灰分。该过程称为表面再生。目前,表面再生过程不如需要那么有效。在表面再生期间,仅被称为软灰的灰分层的外部部分。灰烬的内层,残留的灰分,存活清洁过程。残留的灰分层似乎随时间生长,并且最终可能导致蜡烛过滤器之间的桥接。可以在[1]中的性能历史曲线上,如图1所示,可以注意到残留灰的生长和持续性。过滤系统的基本目标是将气流中固体的浓度降低到可接受的水平最小压降。涉及屏障滤波器的许多较新的设计描述于[2]中。尚未建立强顽固,残留的灰矿床的原因。可以考虑残留灰形成的两个机制是:1)灰分层内颗粒和2)烧结的粘合力[2]。残留的灰分可以在低温以及高温下形成;因此,烧结可以在高温下显着。然而,蜡烛过滤器旨在在高温下操作,并且必须考虑发生烧结的可能性。本研究考虑了在蜡烛过滤器上进入灰分层的未燃烧的碳的问题。这种未燃烧的碳可能是由于不完全的燃烧或系统扰乱。在表面再生期间,如果使用空气,将存在足够量的氧气以在灰分层中发生燃烧。然后,在表面再生期间产生的热量可以导致灰分层烧结。参考文献[2]描述了在英格兰固体,无烟燃料厂中的过滤器上的偶尔燃烧。这些过滤系统的运行在200-300°C的范围内。几个过滤器火灾导致过滤故障。表面再生过程不正确地执行,这归因于脉冲射流故障。研究了通过在过滤器上的灰分沉积物中燃烧未燃烧的碳燃烧产生的热应力[3]。他们的研究描述了从操作PFBC单元中取出的四个灰分样品中的碳浓度。该实验研究表明,当碳含量为16%(重量)时,过滤表面温度的变化可能达到500℃。由于热应力,所得到的温度升高足以预测过滤器故障。

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