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Standardisation of methods for long-term monitoring

机译:长期监测方法的标准化

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A monitoring programme should be designed for duration. This means that methods should not only be appropriate with respect to detection limits and accuracy, but they should also be as simple as possible and they should be documented in such a way that measurements will be comparable over many decades. In this connection, it is particularly important to understand that results are dependent on methods, instruments and procedures. Within the European monitoring network (EMEP) there are several different sampling procedures for the main air components, SO{sub}2, NO{sub}2, SO{sub}4{sup}(2-), NO{sub}3{sup}- + HNO{sub}3, and co-located experiments have therefore been initiated to quantity the difference between the measurements. Reference methods and reference instruments corresponding to the recommendation in the EMEP Manual have been run together with the usual measurements at EMEP sites in several countries. The results are generally satisfactory, especially in the case where identical methods are used. However, there are also some unacceptable differences, e.g. when comparing NO{sub}2 and SO{sub}2 monitors with the reference methods. The monitors do have a main advantage of providing easily accessible data with short time resolution; nevertheless, the accuracy at low concentrations is usually poor. The traditional reference methods need development and simplification in the direction of the more appealing automatic instruments.
机译:应设计监控程序以持续时间。这意味着方法不仅适用于检测限制和准确性,而且它们也应该尽可能简单,并且应该以这样的方式记录,即在数十年中测量将相当的方式。在这方面,理解结果依赖于方法,仪器和程序尤为重要。在欧洲监控网络(EMEP)中,主空气组件有几个不同的采样过程,因此{sub} 2,否{sub} 2,因此{sub} 4 {sup}(2-),否{sub} 3因此,已经启动了共同定位的实验和共同定位的实验到数量测量之间的差异。对应于EMEP手册中的建议的参考方法和参考仪器在若干国家的EMEP网站上运行在一起。结果通常令人满意,特别是在使用相同方法的情况下。然而,也有一些不可接受的差异,例如,在比较NO {sub} 2等{sub} 2时用参考方法监视。监视器确实具有通过短时间分辨率提供易于访问的数据的主要优点;然而,低浓度的准确性通常差。传统的参考方法在更吸引人的自动仪器方向上需要开发和简化。

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