Improvement in the conversion efficiency of single and double junction a-Si solar cells by using high quality p-SiO:H window layer and seed layer/thin n-μc-Si:H bilayer

摘要

We have developed high quality p-type amorphous and microcrystalline SiO:H films by the RF-PECVD method (13.56 MHz) at deposition conditions suitable for use in the fabrication of a-Si solar cells. Previously we have developed seed layer/thin n-μc-Si:H bilayer which reduces significantly the minimum required thickness of n-μc-Si:H layer. By using these materials we have been able to improve the conversion efficiency of single and double junction (a-Si/a-Si) a-Si solar cell. For single junction cells (1.0 cm{sup}2) the initial efficiency till now achieved is 11.6% (V{sub}(oc)=0.91V, J{sub}(sc)=17.7 mA/cm{sup}2 and F.F.=0.72). It is about 1% higher thin that achieved with p-a-SiC:H as the window layer. For double junction cells the initial efficiency achieved is 11.8% (V{sub}(oc)=1.74V, J{sub}(sc)=8.9 mA/cm{sup}2 and F.F.=0.76). There is further scope for achieving higher efficiencies by improving material characteristics and interfaces.