The effective operator approach is applied for the global fitting of the vibrational-rotational line positions of acetylene molecule. About 4470 line positions of the transitions involving vibrational-rotational energy levels up to 4200 cm$+$MIN@1$/ have been used to determine 130 parameters of the effective Hamiltonian. The standard deviation of the fit is 0.0009 cm$+$MIN@1$.
展开▼
机译：有效的操作员方法适用于乙炔分子振动旋转线位置的全局拟合。大约4470个过渡的线路涉及振动旋转能量水平高达4200cm $ + $ min @ 1 $ /已被用于确定有效哈密顿人的130个参数。适合的标准偏差为0.0009厘米$ + $ MIN @ 1 $。
展开▼
