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Synthetic polymers based on carbohydrates: preparation, properties and applications

机译:基于碳水化合物的合成聚合物:制备,性能和应用

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A series of (meth)acryl and maleinimide derivatives of acetylated mono- and disaccharides as well as macromonomers based one cellulose triacetate blocks were synthesized. After radical polymerisation the protecting groups were removed to yield glycopolymers. Hydrophilic silicone rubbers for medical uses were prepared by covalent incorporation of trimethylsilyl (TMS) protected sugar derivatives and subsequent removal of the TMS groups. Azido substituted sucrose was grafted photochemically onto polypropylene surfaces to enhance their wettability. Hydrogels prepared from sucrose methacrylates were reacted with succinic- and maleic acid anhydride to yield efficient adsorbers for bilirubin.
机译:合成了一系列(甲基)丙烯酸和二糖的丙烯酸和二糖的马来酰亚胺衍生物以及基于纤维素三乙酸嵌段的大分子单体。在自由基聚合后,除去保护基团以产生甘甘油聚合物。通过共价掺入三甲基甲硅烷基(TMS)保护的糖衍生物并随后去除TMS基团进行亲水性硅氧烷橡胶。将取代的蔗糖光学嫁接到聚丙烯表面上以增强其润湿性。由蔗糖甲基丙烯酸酯制备的水凝胶与琥珀酸酐反应,得到胆红素的有效吸附剂。

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