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Structure and energetic properties of carbon-mineral adsorbents surface prepared by pyrolysis of methylene chloride

机译:通过二氯甲烷热解制备的碳矿物吸附剂表面的结构和能量性能

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Extensive studies of structure and energetic properties of the surface of the carbosils including from 0.8 to 35percent carbon were undertaken. The structural characteristics of the adsorbents under investigation obtained by nitrogen adsorption and desorption at 77 K, p-nitrophenol adsorption from aqueous solutions and flow microcalorimetry were presented. The results of the studies obtained by the electron paramagnetic resonance EPR and transmission electron microscopy TEM methods were also given. The obtained data allowed to determine morphology and topography of carbon deposits in the studied adsorbents as well as the effect of carbon amount on the modified silica surface on the energetic properties of the obtained complex adsorbents. The general studies, particularly, those on a large scale are of significant importance for further effective usage of original properties of carbon-mineral adsorbents. Knowledge of the complex adsorbent structure including morphology and topography of carbon deposits, surface properties is still poor compared with their present and perspective applications.
机译:进行了对包括0.8至35%碳的碳腈表面的结构和能量性质的广泛研究。提出了通过氮吸附和解吸在77k,p-硝基苯酚从水溶液和流动微离核物中吸附的研究中的吸附剂的结构特征。还给出了通过电子顺磁共振EPR和透射电子显微镜TEM方法获得的研究结果。所获得的数据允许确定所研究的吸附剂中的碳沉积物的形态和地形以及改性二氧化硅表面对所得复合吸附剂的能量性质的碳量的影响。一般研究,特别是那些大规模的研究对于进一步有效使用碳 - 矿物吸附剂的原始性质具有重要意义。了解包括碳沉积物形态和地形的复杂吸附剂结构,与目前和透视应用相比,表面性质仍然差。

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