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BIOMINERAL FILM COATING ON TITANIUM ELECTRODE IN AQUEOUS SOLUTION

机译:水溶液中钛电极上的生物矿物薄膜涂层

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Electrolytic method was applied to calcium phosphate coating on titanium plates as an excellent technique for high density and intensive contact of coated films on biomaterials. The effect of H_2O_2 as oxidation reagent on coating characteristics was examined to obtain biomineral films. Solution was containing 7.0 X 10~(-3) mol/dm~3 of CaCl_2 and 3.0 X 10~(-2) of Ca(H_2PO_4)_2, kept at 55 deg C. All deposits were hydroxyapatite (HAp) in this study, independent of H_2O_2 concentration, applied cathodic potential and solution pH. In the case of H_2O_2 addition, an increase in cathode current started at the low potential, namely, ca. -0.2 V (vs. SCE). In contrast, the current increased at more than ca. -1.4 V in the solution without H_2O_2 addition. H_2O_2 appeared to be an effective reagent for increasing nucleation density and improving adhesion of deposits on titanium plates.
机译:将电解方法应用于钛板上的磷酸钙涂层,是涂层膜对生物材料涂膜高密度和密集接触的优异技术。研究了H_2O_2作为氧化试剂对涂层特性的影响,得到生物矿物薄膜。溶液含有7.0×10〜(-3)摩尔/ dm〜3的CaCl_2和3.0×10〜(-2)的Ca(H_2PO_4)_2,保持在55℃的Ca-55℃。所有沉积物在本研究中均为羟基磷灰石(HAP) ,独立于H_2O_2浓度,施加的阴极电位和溶液pH。在H_2O_2的情况下,阴极电流的增加在低电位下开始,即CA. -0.2 v(与sce)。相比之下,电流在比CA多增加。 -1.4 V在溶液中没有H_2O_2添加。 H_2O_2似乎是一种有效的试剂,用于增加成核密度并改善沉积物对钛板的粘附性。

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