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GAS STORAGE IN ACTIVATED CARBONS OBTAINED FROM BIOMASS DERIVED HYDROTHERMALLY CARBONIZED CARBONS

机译:从生物量获得的活性炭中的气体储存来自生物量衍生的水热碳化碳

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Introduction In recent years hydrothermal carbonization (HTC) has demonstrated its capability of converting biomass into carbon materials (called hydrochar) under very mild processing conditions [1]. Unfortunately, the hydrochar materials have the drawback of possessing almost no porosity, unless it is synthesized in the presence of a template or subjected to additional heat treatment at higher temperature [2]. To make possible the use of porous materials based on hydrochar in emergent applications, such as gas storage (natural gas, CO_2 or hydrogen storage) or electrical energy storage (such as supercapacitors), the synthesis of highly microporous carbon materials based on these materials is required. As reviewed in detail in a previously published study [3], chemical activation by KOH and NaOH is a way to successfully prepare highly microporous activated carbons (ACs) from very different precursors. Therefore, it is challenging to develop high micropore volumes in this type of material.
机译:近年来,近年来水热碳化(HTC)证明了在非常温和的加工条件下将生物质转化为碳材料(称为水)的能力[1]。遗憾的是,氢淀粉材料具有几乎没有孔隙率的缺点,除非在模板存在下合成或在较高温度下进行额外的热处理[2]。为了使基于水的多孔材料基于漏油应用,例如储气储气(天然气,CO_2或储氢)或电能存储(如超级电容器),基于这些材料的高度微孔碳材料的合成是必需的。如先前公布的研究中的详细审查[3],KOH和NaOH的化学活化是从非常不同的前体成功制备高度微孔活性炭(ACS)的一种方法。因此,在这种类型的材料中开发高微孔体积是挑战性的。

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