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DESIGN AND COMBINATION OF CARBON MATERIALS FOR ADVANCED LITHIUM SULFUR BATTERIES

机译:高级锂硫电池碳材料的设计与组合

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Lithium-sulfur (Li-S) batteries are currently being explored intensely due to their high theoretical specific energy density and low cost [1]. However, the area] sulfur loading of electrodes is usually less than 2.0 mg cm~(-2), which leads to low areal capacity that does not even outperform standard Li-ion batteries (4 mAh cm~(-2)) [2]. For conventional aluminum-based sulfur electrodes, it is almost impossible to obtain high sulfur loaded electrodes by increasing the electrode thickness, because thick electrode will cause low sulfur utilization as a result of limited electrode kinetics for both lithium ions and electrons [3]. In this regard, using three-dimensional (3D) current collectors with interlinked electron and ion channels will be ideal for achieving high sulfur-loaded and high performance Li-S batteries.
机译:由于其高理论特异性能量密度和低成本,目前正在探讨锂 - 硫(LI-S)电池的电池[1]。然而,电极的硫加载通常小于2.0mg cm〜(-2),这导致低的面积容量,甚至不超过标准的锂离子电池(4 mah cm〜(-2))[2 ]。对于常规的铝基硫电极,几乎不可能通过增加电极厚度来获得高硫负载电极,因为厚电极由于锂离子和电子的电极动力学的有限电极动力学而导致低硫使用[3]。在这方面,使用具有相互连接的电子和离子通道的三维(3D)集电器将是实现高硫加载和高性能LI-S电池的理想选择。

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