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Flow Properties and Durability Assessment in Wood-Plastic Composites

机译:木塑复合材料中的流动性能和耐久性评估

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Wood flour is gaining popularity as an established filler in thermoplastic composites. The intrinsic properties of wood flour combined with resin formulation and type of coupling agent determine the flow properties and the melt processing conditions of the composite for further applications and use. In this work, commercial types of maleated coupling agents with varying molecular weight and MAH graft content were tested to improve the filler-matrix interface adhesion and durability of polypropylene (PP) wood composites. The heat distortion temperature (HDT) has indicated considerable gain in stiffness of the PP filled with wood flour. Thermally aged samples at controlled temperature and times presented gradual increase in stiffness. Further assessment of thermal stability using oxidative induction time (OIT) for different formulations indicated changes in the oxidation mechanism when comparing neat PPs OITs to wood-plastic composites (WPC). Ultraviolet stability was evaluated after weather-o-meter testing in terms of the sample yellowness using DE shifts determined by the Color Test. Power law parameters determined by capillary rheometer have shown no major deviations in flow properties for the wood composites compared to the neat resins. The results assure good moldability conditions for all of the formulations investigated although in some cases melt consistency may be quite sensitive to testing temperature.
机译:木粉是热塑性复合材料中已建立的填料的普及。木粉的固有性质与树脂制剂联合和偶联剂的类型决定了复合材料的流动性和熔体加工条件,以进行进一步的应用和使用。在这项工作中,测试了具有不同分子量和MAH接枝含量的原始偶联剂的商业类型,以改善聚丙烯(PP)木复合材料的填充基质界面粘附和耐久性。热变形温度(HDT)表示填充有木面粉的PP的刚度相当大的增益。受控温度和时间的热老化样品呈现刚度逐渐增加。进一步评估使用氧化诱导时间(OIT)进行不同配方的热稳定性,当将纯PPS液体与木塑复合材料(WPC)进行比较时,不同配方的变化表明氧化机理的变化。在使用由颜色测试确定的de移位的样品yellowness方面的天气o-meter测试后评估紫外稳定性。由毛细管流变仪确定的功率法参数表明,与整齐的树脂相比,木质复合材料的流动性质没有主要偏差。结果确保所有研究的配方的良好可模塑条件,尽管在某些情况下,熔体稠度可能对测试温度非常敏感。

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