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Effect of atmosphere on the sintering and grain growth of tin oxide

机译:大气对氧化锡烧结和籽粒生长的影响

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High purity SnO{sub}2 powder (>99.9%) was compacted in cylindrical pellets and sintered in atmospheres of dry argon, argon with water vapor, oxygen and CO{sub}2 using 10°C/min up to 1200°C or isotherms in the range of 1000 to 1200°C. Time,temperature and sintering atmosphere have large influence on grain growth and low influence on densification of this oxide. Surface diffusion is the dominant mechanism up to 1200°C and evaporation-condensation is dominant above 1200°C. The maximum linearshrinkage observed was about 2.0% and attributed to structural rearrangement of particles due to high capillary stresses developed with neighboring particles.
机译:高纯度SnO {Sub} 2粉末(> 99.9%)在圆柱形粒料中压实,并在干燥氩气的大气中烧结,使用10°C / min的水蒸气,氧气和CO} 2氩气,氧气和CO} 2可达1200°C或等温物在1000至1200°C的范围内。时间,温度和烧结气氛对晶粒生长和对该氧化物致密化的影响很大。表面扩散是高达1200℃的主要机制,蒸发 - 冷凝优于1200℃以上。观察到的最大线性分号约为2.0%,由于具有相邻颗粒的高毛细管应力,颗粒的结构重排。

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