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High Pressure Phases and Properties of C_60

机译:C_60的高压阶段和性质

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Fullerenes are molecular carbon solids with very strong intramolecular bonds but very weak intermolecular ones. However, a large number of reactive intramolecular double bonds on each molecule also enables C_60 to form covalent intermolecular bonds under pressure. This implies that a )pressure has a large effect on the physical properties of C_60 in its pristine zero-pressure forms, and b)treatment at high pressure and high temperature leads to the formation of new, polymeric phases with covalent intermolecular bonds, phases which have new, interesting properties and which may have practical applications in the future. I discuss here some recent experimental results on the structure and properties of C_60 under high pressure.
机译:富勒烯是分子碳固体,具有非常强的分子内键,但分子间粘合非常弱。然而,每个分子上的大量反应分子内双键也使C_60能够在压力下形成共价分子间键。这意味着a)压力对其原始零压力形式的C_60的物理性质具有很大的影响,B)在高压和高温下处理导致形成新的聚合物相对于共价分子结合,阶段的阶段有新的有趣的财产,未来可能具有实际应用。我在这里讨论了最近在高压下C_60的结构和性质的一些实验结果。

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