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The Evaluation of the Corrosion Resistance of Metallic Substrates Protected By a Hydrophobic Coating

机译:疏水涂层保护金属基材耐腐蚀性的评价

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With the advent of polymeric materials, various uses for these materials have been discovered in the quest to best utilize their unique characteristics. One property that a few polymers possess is hydrophobicity; that is water repelling. Consequently, one particular use for hydrophobic materials is in the area of corrosion protection. When applied as a coating material, hydrophobic polymers, theoretically, should provide excellent protection against corrosive environments. In order to ascertain the performance of hydrophobic materials in corrosion service, metallic substrates of aluminum, copper, and steel were coated with a hydrophobic coating termed conformal and subjected to a variety of intensive analytical examinations including Electrochemical Impedance Spectroscopy, real-time field studies, and scanning electron microscopy. To be able to gage the relative performance of the conformal coat, it was necessary to test similar uncoated metallic substrates as well as similar substrates treated with a non-hydrophobic corrosion preventative coat. This allowed direct comparisons to be made between the conformal coat and other commercially available coating products while allowing for an uncoated substrate to act as a baseline reference (i.e. a control). The results of these experiments show that the performance of conformal as a preventative measure against corrosion were below expectations, especially in comparison to other commercially available non-hydrophobic coatings. This is most likely due to inadequate adhesion at the polymer-metal substrate interface. Preliminary results show that significant improvements in corrosion resistance occur through the use of a base coating though the cause for this improvement cannot determined at this time.
机译:随着聚合物材料的出现,在寻求最佳利用它们独特的特征中发现了这些材料的各种用途。少数聚合物具有疏水性的一个性质;那是水排斥。因此,疏水材料的一个特定用途是在腐蚀保护面积。当用作涂料时,理论上疏水聚合物,应提供优异的防腐蚀环境保护。为了确定腐蚀服务中疏水材料的性能,涂覆铝,铜和钢的金属基板,涂覆疏水涂层,称为共形化,并进行各种密集的分析检查,包括电化学阻抗光谱,实际场研究,和扫描电子显微镜。为了能够测量共形涂层的相对性能,有必要测试类似的未涂覆的金属底物以及用非疏水性腐蚀预防涂层处理的类似底物。这允许在适形涂层和其他市售涂料产品之间进行直接比较,同时允许未涂覆的基材充当基线参考(即对照)。这些实验的结果表明,作为防止腐蚀的预制措施的性能低于预期,特别是与其他市售的非疏水涂层相比。这很可能是由于聚合物 - 金属基材界面处的粘附不足。初步结果表明,通过使用碱涂层,虽然此时不能确定该改善的原因,但耐腐蚀性的显着改善。

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