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Ionic-liquid based electrochemical ethylene sensor

机译:基于离子液体的电化学乙烯传感器

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We present an electrochemical ethylene sensor that exploits a thin ionic-liquid (IL) layer as electrolyte. ILs are fluids that completely consist of ions at room temperature and have emerged as extremely promising electrolytes for the following reasons: first, the vapor pressure is practically negligible and therefore even thin films remain stable over time. Second, the solubility of ethylene is higher compared to water leading to an enhanced current. Finally, a thin layer leads to effective ethylene diffusion and therefore enhanced sensor current and response time. We show that ethylene can be detected in a specific potential window and a linear response up to 200 ppm with a detection limit of 25 ppm has been achieved. We foresee that our approach could be extended to other gases and ILs could become widespread in electrochemical gas sensors.
机译:我们提出了一种电化学乙烯传感器,其利用薄离子 - 液体(IL)层作为电解质。 ILS是在室温下完全由离子完全组成的流体,并且由于以下原因出现为极其有前景的电解质:首先,蒸气压几乎可以忽略不计,因此甚至薄膜随时间仍然稳定。其次,与导致增强电流的水相比,乙烯的溶解度更高。最后,薄层导致有效的乙烯扩散,因此提高了传感器电流和响应时间。我们表明,在特定潜在窗口中可以检测到乙烯,并且已经实现了高达200ppm的线性响应,并且已经实现了25ppm的检测限。我们预见,我们的方法可以扩展到其他气体,ILS可能在电化学气体传感器中普及。

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