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Cavitation Erosion of Polyurea Composite Coatings

机译:聚脲复合涂层的空蚀

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Polyurea (PU) was synthesized by reacting oligomeric poly (tetramethylene oxide) (PTMO) diamines (Versalink, Air Products) with aromatic 4,4’-Methylenediphenyldiisocyanate (Isonate 143L Modified MDI, Dow Chemicals). Two Versalink prepolymers were used: VP-1000, VP-650, where 1000, and 650 refer to the molecular weight of the PTMO repeating units. PU-105 and PU-605 were synthesized by mixing VP-1000 and VP-650 with Isonate 143L. It has been observed that the temperature within the polyurea coating under cavitation erosion could increase to a considerable amount, resulting in degradation of its mechanical properties and an accelerated onset of failure. To improve the relevant thermo-mechanical properties of polyurea, milled carbon fibers of 3% and 10% volume ratios were added to the PU-605 matrix. In the present work, accelerated cavitation erosion tests based on ASTM-G32 standard were performed to study the effect of substrate, coating thickness, and formulation on cavitation resistance. The substrates of interest were aluminum and carbon fiber reinforced polymer (CFRP) plates. The experimental investigations were done on two coating thicknesses, 0.5 mm and 1 mm. Surface roughness measurements were performed after regular exposure time intervals using the stylus profilometer. Results showed that the cavitation erosion of polyurea coated substrates are different depending on the chemistry of the coating and properties of the substrate. PU-105 was more susceptible to cavitation erosion. Average depth of erosion for the composite formulation with 10% volume ratio of milled carbon fibers, was among the highest after 3 hours of erosion test.
机译:聚脲(PU)是通过低聚聚四氢呋喃(PTMO)二胺(Versalink,Air Products)与芳香族4,4'-亚甲基二苯基二异氰酸酯(Isonate 143L Modified MDI,Dow Chemicals)反应而合成的。使用了两种Versalink预聚物:VP-1000,VP-650,其中1000和650是指PTMO重复单元的分子量。通过将VP-1000和VP-650与Isonate 143L混合来合成PU-105和PU-605。已经观察到,在气蚀作用下的聚脲涂层内的温度可能升高到相当大的水平,从而导致其机械性能的降低和加速失效的开始。为了改善聚脲的相关热机械性能,将3%和10%体积比的研磨碳纤维添加到PU-605基质中。在当前的工作中,基于ASTM-G32标准进行了加速空化腐蚀试验,以研究基材,涂层厚度和配方对耐空蚀性的影响。感兴趣的基材是铝和碳纤维增强聚合物(CFRP)板。实验研究是在两种涂层厚度(0.5毫米和1毫米)上进行的。在一定的曝光时间间隔后,使用测针轮廓仪进行表面粗糙度测量。结果表明,聚脲涂覆的基材的空化侵蚀取决于涂层的化学性质和基材的性能。 PU-105对空蚀更敏感。磨碎碳纤维体积比为10%的复合配方的平均腐蚀深度在3小时的腐蚀测试后最高。

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