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Kinetics of Scrap Melting in Iron-Carbon Bath

机译:铁炭浴中废料熔化的动力学

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The melting kinetics of scrap is a limiting factor in controlling the temperature trajectory and scrap ratio of BOF process as well as the energy consumption and productivity of EAF steelmaking. Prediction of the melting rate of scrap, the mass transfer coefficient of carbon, and heat transfer coefficient between the melt and scrap can provide a theoretical basis for the process modeling of BOF and EAF. In this paper, the interface between melt and scrap in melting process is analyzed, and the moving boundary layer concept is optimized. Through Fick's law and Fourier equation state, combined with the heat and mass balance of moving interface, the theoretical analysis model of scrap melting is established and programmed. The effects of bath temperature on the melting behavior of scrap in the liquid melt are studied. The results show that as the bath temperature increases, the formation time and maximum thickness of solidified layer decrease; furthermore, the time to reach the final stable melting rate and the initial heat transfer coefficient decreases. However, the final stable melting rate increases; moreover, the final stable heat transfer coefficient and mass transfer coefficient initially increase and then decrease.
机译:废料的熔融动力学是控制BOF工艺的温度轨迹和废料比率以及电炉炼钢的能耗和生产率的限制因素。预测废料的熔化速率,碳的传质系数以及熔体和废料之间的传热系数可为转炉和电弧炉的工艺建模提供理论依据。本文分析了熔化过程中熔体与废料之间的界面,并优化了移动边界层的概念。通过菲克定律和傅立叶方程状态,结合运动界面的热量和质量平衡,建立并编程了废料熔化的理论分析模型。研究了熔池温度对废料在液态熔体中熔融行为的影响。结果表明,随着熔池温度的升高,凝固层的形成时间和最大厚度减小;随着熔池温度的升高,凝固层的最大厚度减小。此外,达到最终稳定的熔融速率和初始传热系数的时间减少了。但是,最终的稳定熔化速率会增加;此外,最终的稳定传热系数和传质系数先增大然后减小。

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