An Effective Rate Equation Model for Energy Transfer from Ruthenium Trisbipyridine to Anthracene

机译：能量从三联吡啶钌转化为蒽的有效速率方程模型

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We employ the well-studied donor/acceptor system consisting of tris(2,2′-bipyridine)ruthenium(II) and anthracene to validate a simple rate equation model for energy transfer and subsequent dimerization of the excited anthracene acceptor.

机译：我们采用了经过深入研究的由三（2,2'-联吡啶）钌（II）和蒽组成的供体/受体体系，以验证能量转移和随后的激发蒽受体二聚化的简单速率方程模型。

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《IEEE Research and Applications of Photonics in Defense Conference》|2019年|1-4|共4页
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Timothy M. Pritchett; Ryan M. ODonnell; Thomas N. Rohrabaugh;
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Mathematical model; Absorption; Energy exchange; Kinetic theory; Delay effects; Stationary state; Computational modeling;

机译：数学模型吸收能量交换运动学理论时滞效应平稳状态计算模型;

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1. Distance-independent photoinduced energy transfer over 1.1 to 2.3 nm in ruthenium trisbipyridine-fullerene assemblies [J] . Frederique Chaignon, Javier Torroba, Errol Blart, New Journal of Chemistry . 2005,第10期

机译：钌三三联吡啶-富勒烯组件中与距离无关的光致能量转移，范围为1.1至2.3 nm
2. Intramolecular Electronic Energy Transfer in a Pyrene-Labeled Ruthenium(II)-Trisbipyridine Hemicage Complex [J] . Jean-Ernest Sohna Sohna, Virginie Carrier, Frederic Fages, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第23期

机译：yr标记的钌（II）-Trisbipyridine缩血配合物中的分子内电子能量转移
3. Supramolecular and intramolecular energy transfer with ruthenium-anthracene donor-acceptor couples: Salt bridge versus covalent bond [J] . Freys J.C., Wenger O.S. European journal of inorganic chemistry . 2010,第35期

机译：钌-蒽供体-受体对的超分子和分子内能量转移：盐桥与共价键
4. An Effective Rate Equation Model for Energy Transfer from Ruthenium Trisbipyridine to Anthracene [C] . Timothy M. Pritchett, Ryan M. ODonnell, Thomas N. Rohrabaugh IEEE Research and Applications of Photonics in Defense Conference . 2019

机译：一种有效率方程模型，用于从钌三吡啶与蒽的能量转移
5. A simple effective model for calculating electron transfer rates in proteins, and an analysis of the evolutionary engineering principles used to create biological electron transfer systems. [D] . Page, Christopher Charles. 2001

机译：一个简单有效的模型，用于计算蛋白质中的电子转移速率，并分析了用于创建生物电子转移系统的进化工程原理。
6. Consideration of dipole orientation angles yields accurate rate equations for energy transfer in the rapid diffusion limit. [O] . J V Mersol, H Wang, A Gafni, 1992

机译：偶极子定向角的考虑产生了在快速扩散极限中能量转移的精确速率方程。
7. This article presents a new numerical model describing the behaviour of a thermally thick wood sample exposed to high solar heat flux (above 1 MW/m2). A preliminary study based on dimensionless numbers is used to classify the problem and support model building assumptions. Then, a model based on mass, momentum and energy balance equations is proposed. These equations are coupled with liquid-vapour drying model and pseudo species biomass degradation model. By comparing to a former experimental study, preliminary results have shown that these equations are not enough to accurately predict biomass behaviour under high solar heat flux. Indeed, a char layer acting as radiative shield forms on the sample exposed surface. In addition to this classical set of equations, it is mandatory to take into account radiation penetration into the medium. Furthermore, as biomass contains water, medium deformation consecutively to char steam gasification must also be implemented. Finally, with the addition of these two strategies, the model is able to properly capture the degradation of biomass when exposed to high radiative heat flux over a range of sample initial moisture content. Additional insights of biomass behaviour under high solar heat flux were also derived. Drying, pyrolysis and gasification fronts are present at the same time inside of the sample. The coexistence of these three thermochemical fronts leads to char gasification by the steam produced from drying of the sample, which it is the main phenomenon behind medium ablation. [O] . Pozzobon, Victor, Salvador, Sylvain, Bézian, Jean Jacques 2018

机译：本文提供了一个新的数值模型，该模型描述了暴露于高太阳热通量（高于1 / MW / m2）的热厚木材样品的行为。基于无量纲数的初步研究用于对问题进行分类并支持模型构建假设。然后，提出了一种基于质量，动量和能量平衡方程的模型。这些方程式与液体蒸汽干燥模型和假物种生物质降解模型耦合。通过与以前的实验研究进行比较，初步结果表明，这些方程不足以准确预测高太阳热通量下的生物量行为。的确，在样品暴露的表面上形成了充当辐射屏蔽层的炭层。除了这套经典的方程式之外，还必须考虑到辐射向介质的渗透。此外，由于生物质中含有水，因此还必须在炭蒸气汽化后进行连续的介质变形。最后，通过添加这两种策略，该模型能够在一定范围的样品初始水分含量下暴露于高辐射热通量的情况下，正确捕获生物质的降解。还得出了在高太阳热通量下生物量行为的其他见解。样品内部同时存在干燥，热解和气化前沿。这三个热化学前沿的共存会导致样品干燥产生的蒸汽产生焦炭气化，这是介质烧蚀的主要现象。
8. Internal Energy Transfer and Dissociation Model Development using Accelerated First-Principles Simulations of Hypersonic Flow Features. [R] . Schwartzentruber, T. E. 2013

机译：利用高超声速流动特征的加速第一原理模拟开发内能量转移和解离模型。

An Effective Rate Equation Model for Energy Transfer from Ruthenium Trisbipyridine to Anthracene

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