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Experimental Study on the Thermal Insulation and Seawater Corrosion Resistance Effects of Silane-Nanoceramic Coatings in Subsea Riser

机译:海底提升管中硅烷-纳米陶瓷涂层的隔热和耐海水腐蚀作用的实验研究

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摘要

In China's Bohai Sea, there is a large amount of heavy and viscous oil needs to be produced. At present, the steam huff and puff is currently the most effective means of producing heavy oil reservoir, and the riser system is a conduit system that connects the subsea wellhead and the rig and also plays an important role in the circulation of steam. Thus, as an important circulation channel in thermal recovery well in offshore heavy oilfield, the riser needs to have heat insulation effect. The silane-nanoceramic composite as a new type of heat insulation coating material has the advantages of low thermal conductivity, high insulation effect and seawater corrosion resistance than other insulation coatings. This paper firstly utilizes infrared heating technology to test the thermal insulation performance of ordinary nanoceramics and silanenanoceramic coatings. Then the actual service condition of thermal insulation coating is simulated by using the test of the riser heating device. The thermal barrier effect of three types of riser thermal barrier coatings is evaluated, the influence of coating structure, and coating thickness on the insulation effect of silane-nanoceramic composite coating are also analyzed. Considering the corrosion resistance of the riser coating system in seawater, this paper also tests the anti-seawater immersion properties of the coating and salt spray corrosion resistance, and uses two field experiments to verify the actual results. The results figure out that silane-nanoceramic ceramic coatings have better thermal insulation properties than ordinary ceramic coatings. The thermal conductivity of silane-nanoceramic can be as low as 0.028 W/mK, and heat insulation rate can reach more than 70% when the inner temperature is kept at 350°C, so the silane-nanoceramic coatings have obvious advantages compared with other insulating materials. External wall spraying coating has higher insulation effect. With the increase of coating thickness, the insulation effect is more significant. The insulation preservation rate can be more than 80%, when coating thickness reached 500um. The corrosion resistance experimental results show that the coating anticorrosive life rises with the increase of the coating thickness and the field experiments prove the silane-nanoceramic composite coating has good seawater corrosion resistance, salt spray resistance and antifouling performance.
机译:在中国的渤海,需要生产大量的重型和粘性油。目前,蒸汽Huff和Puff目前是生产重油储层的最有效手段,并且提升系统是连接海底井口和钻机的导管系统,并且在蒸汽的循环中也起着重要作用。因此,作为在海上重油场中热回收井中的重要循环通道,提升机需要具有隔热效果。硅烷纳米陶瓷复合材料作为一种新型的隔热涂层材料具有低导热性,高绝缘效果和海水耐腐蚀性的优点。本文首先利用红外线加热技术来测试普通纳米陶瓷和硅烷陶瓷涂层的隔热性能。然后通过使用提升管加热装置的测试模拟隔热涂层的实际服务条件。还分析了三种提升管热阻挡涂层的热阻挡效应,还分析了涂层结构的影响和涂层厚度对硅烷纳米陶瓷复合涂层的绝缘效果。考虑到海水中提升管涂料系统的耐腐蚀性,本文还测试了涂层和盐雾腐蚀性的抗海水浸泡性能,并使用了两个现场实验来验证实际结果。结果弄清楚硅烷 - 纳米陶瓷涂料具有比普通陶瓷涂层更好的隔热性能。硅烷纳米陶瓷的导热率可以低至0.028W / mk,当内部温度保持在350℃时,隔热速率可达到70%以上,因此硅烷纳米陶瓷涂层与其他相比具有明显的优势绝缘材料。外墙喷涂涂层具有更高的绝缘效果。随着涂层厚度的增加,绝缘效果更为显着。当涂层厚度达到500um时,绝缘保存速率可能大于80%。耐腐蚀实验结果表明,涂​​层防腐寿命随着涂层厚度的增加而上升,野外实验证明了硅烷 - 纳米陶瓷复合涂层具有良好的海水耐腐蚀性,盐雾性和防污性能。

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