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Development of nanoparticulate coatings for high-strength steel alloys during the press hardening process

机译:冲压硬化过程中用于高强度钢合金的纳米颗粒涂层的开发

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Development of cost-effective steel coatings promotes the optimization of the press hardening process. The latter utilizes austenite-martensite transition to achieve a high tensile strength of steels. Upon such transition a steel plate is quenched from ca. 950 °C down to 200 °C within a minute and simultaneously stamped by a press. However, intense rust formation hinders further processing of stamped details unless protective measures are applied. In this contribution a strategy for the application of a protective coating using water-based nanoparticle dispersions is presented. While multimodal particle size distribution aimed for low shrinkage of the green biscuit, chemical composition of the applied dispersions was fine-tuned for an optimal temperature cycle for the press hardening process. In contrast to previously reported coatings based on the classical sol-gel process, the protective ability of the particulate silicate coatings reaches up to 950 °C as demonstrated by thermogravimetric analysis. The reported coating system can be compared to the standard Usibor® coating, which is widely used nowadays in industry. To illustrate the issue, results on corrosion potential and corrosion current, as well as on the impedance response are reported here. Although Usibor®-coatings demonstrate better passivation in aqueous media, the temperature treatment cycle of the press hardening can be considerably accelerated in case of the silicate coatings.
机译:具有成本效益的钢涂层的开发促进了压制硬化工艺的优化。后者利用奥氏体-马氏体转变来实现钢的高拉伸强度。在这样的转变后,钢板从约10℃淬火。在一分钟内从950°C降至200°C,并同时通过压力机进行冲压。但是,除非采取保护措施,否则严重的锈蚀会阻碍冲压件的进一步加工。在该贡献中,提出了使用水基纳米颗粒分散体来施加保护涂层的策略。尽管多峰粒度分布旨在降低生坯饼干的收缩率,但已对分散体的化学组成进行了微调,以实现压制硬化过程的最佳温度周期。与以前报道的基于经典溶胶-凝胶工艺的涂料相反,颗粒硅酸盐涂料的保护能力可达到950°C,如通过热重分析所证明的那样。所报导的涂料体系可与当今工业上广泛使用的标准Usibor®涂料进行比较。为了说明这个问题,此处报告了有关腐蚀电位和腐蚀电流以及阻抗响应的结果。尽管Usibor®涂层在水性介质中表现出更好的钝化性能,但在使用硅酸盐涂层的情况下,可以大大加快压制硬化的温度处理周期。

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