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An Improved Approach for Analyzing the Oxygen Compatibility of Solvents and Other Oxygen-Flammable Materials for Use in Oxygen Systems

机译:分析用于氧气系统的溶剂和其他氧气易燃材料的氧气相容性的改进方法

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Solvents used to clean oxygen system components must be assessed for oxygen compatibility because incompatible residue or fluid inadvertently left behind within an oxygen system can pose a flammability risk. The most recent approach focused on solvent ignition susceptibility to assess the flammability risk associated with these materials. Previous evaluations included ambient pressure liquid oxygen (LOX) mechanical impact testing (ASTM G86) and autogenous ignition temperature (AIT) testing (ASTM G72). The goal in this approach was to identify a solvent material that was not flammable in oxygen. As environmental policies restrict the available options of acceptable solvents, it has proven difficult to identify one that is not flammable in oxygen. A more rigorous oxygen compatibility approach is needed in an effort to select a new solvent for NASA applications. NASA's White Sands Test Facility proposed an approach that acknowledges oxygen flammability yet selects solvent materials based on their relative oxygen compatibility ranking, similar to that described in ASTM G63-99. Solvents are selected based on their ranking with respect to minimal ignition susceptibility, damage, and propagation potential, as well as their relative ranking when compared with other solvent materials that are successfully used in oxygen systems. Based on these comparisons, in which solvents exhibited properties within those ranges seen with proven oxygen system materials, it is believed that Solstice PR L-14780, and Vertrel MCA would perform well with respect to oxygen compatibility.
机译:必须评估用于清洁氧气系统组件的溶剂的氧气相容性,因为氧气系统内不相容的残留物或无意间遗留的液体可能会引起燃烧危险。最新方法集中于溶剂着火敏感性,以评估与这些材料相关的可燃性风险。先前的评估包括环境压力液氧(LOX)机械冲击测试(ASTM G86)和自燃着火温度(AIT)测试(ASTM G72)。这种方法的目标是确定一种在氧气中不可燃的溶剂材料。由于环境政策限制了可接受的溶剂的可用选择,因此事实证明很难识别出在氧气中不易燃的溶剂。为了为NASA应用选择一种新的溶剂,需要一种更加严格的氧气相容性方法。 NASA的White Sands测试设施提出了一种方法,该方法承认氧气易燃,但仍根据其相对氧气相容性等级来选择溶剂材料,类似于ASTM G63-99中所述。选择溶剂时要根据它们在最小点火敏感性,破坏和传播潜能方面的等级,以及与氧气系统中成功使用的其他溶剂材料相比的相对等级。基于这些比较,其中溶剂表现出在经证实的氧气系统材料中可以看到的那些范围内的性能,据信Solstice PR L-14780和Vertrel MCA在氧气相容性方面表现良好。

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