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The role of Mn in photorefractive LiNbO_3

机译:Mn在光折变LiNbO_3中的作用

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The dynamic range, sensitivity and dark decay of holographic recording in LiNbO_3 crystals doped with 0.2 atomic% Mn with different oxidation states have been measured. The sensitivity is 0.5 cm/J and found to be independent of the oxidation states, while the largest M/# obtained is 12/mm (extraordinary light polarization, light wavelength 458 nm). The dark decay time constants of non-fixed holograms stored in these LiNbO_3:Mn crystals obey an Arrhenius-type dependence on the absolute temperature with an activation energy of about 1.0 eV, and the dark decay is several orders of magnitude slower than that of LiNbO_3:Fe with comparable doping levels. In contrast to LiNbO_3:Fe, the dominant dark decay mechanism in highly-doped LiNbO_3:Mn crystals is due to proton compensation rather than electron tunneling.
机译:测量了掺杂0.2原子%Mn的LiNbO_3晶体在不同氧化态下的全息记录的动态范围,灵敏度和暗衰减。灵敏度为0.5 cm / J,并且与氧化态无关,而获得的最大M /#为12 / mm(非常规偏振,光波长458 nm)。储存在这些LiNbO_3:Mn晶体中的非固定全息图的暗衰减时间常数遵循绝对温度的Arrhenius型依赖性,其活化能约为1.0 eV,并且暗衰减比LiNbO_3慢几个数量级。 :Fe具有可比的掺杂水平。与LiNbO_3:Fe相比,高掺杂LiNbO_3:Mn晶体的主要暗衰变机理是由于质子补偿而不是电子隧穿。

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