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Functionalization of Textile Substrates by NIR Initiated Photopolymerization of Multi-Functional Acrylic Esters

机译:NIR引发的多功能丙烯酸酯的光聚合对纺织品基材的功能化

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Conventional textile polymer coatings have been often applied as homogeneous solutions or heterogeneous aqueous dispersions using energy intensive thermal drying techniques to solidify the coating. This is either physical drying by removing the coating solvent or chemical curing of the coating components. Nevertheless, both processes require higher temperatures provided by convection dryers and consequently they are cost-intensive and time consuming. On the other hand, radiation induced polymerization of textile coatings represents an ecological and economical altemative using LEDs as energy saving radiation source. LEDs have been available from the UV up to the near infrared (NIR) region. NIR-LED arrays may possess some benefits compared to UV LEDs; that is a larger curing depth profile, the possibility to embed UV absorbers as well as yellow pigments, and initiation of thermal events by deactivation of the excited state that additionally functions as an absorber in the coating formulation.
机译:常规的纺织聚合物涂料通常使用能量强化热干燥技术作为均相溶液或异质水分散体施加以固化涂层。通过除去涂料组分的涂层溶剂或化学固化,这是物理干燥。然而,两个过程需要对流干燥器提供的更高温度,因此它们是成本密集和耗时的。另一方面,纺织涂层的辐射诱导的聚合代表了使用LED作为节能辐射源的生态和经济型的替解。 LED已从UV到近红外(NIR)区域提供。与UV LED相比,NIR-LED阵列可能具有一些好处;这是一种较大的固化深度曲线,可以将UV吸收剂以及黄色颜料嵌入UV吸收剂,并通过去激活作为在涂料制剂中的吸收器中的激发状态来引发热事件。

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