An on-line monitoring technique for Trace Gases in Atmosphere Based on Differential optical absorption spectroscopy

摘要

Differential optical absorption spectroscopy (DOAS) has become a widely used method to measure trace gases in the atmosphere. The concentrations of trace gases can be retrieved by fitting differential absorption spectra with standard differential absorption cross-section using the linear least-square method. The basic principle of DOAS is introduced. The construction of DOAS on-line monitoring system is designed and the retrieval method of trace gases concentration based on the principle of least-squares is discussed. The properties of DOAS system are tested by experiments. The advantages of DOAS system used in atmosphere quality monitoring are shown.