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Hydrothermal Synthesis and Photoluminescent Properties of Zinc Tungstate Nano/Microstructures

机译:钨酸锌纳米/微结构的水热合成及光致发光性能

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Different Zinc tungstate (ZnWO4) nanostructures were controllably synthesized via facile hydrothermal method in the presence of surfactant polyethylene glycol 20000 (PEG-20000). During the synthesis, cheap and simple inorganic salts were used as precursors. The shape and size of ZnWO4 nano/microstructures can be well controlled by the dosage of surfactant, the pH value of reaction system and other hydrothermal parameters. Apart from structural and morphological characterizations of the ZnWO4 nano/microstructures, the composition and the photoluminescent (PL) properties of typical samples have also been investigated by powder X-ray diffraction pattern and fluorescence spectrophotometer, respectively. The results indicated that all the products of ZnWO4 with different morphologies exhibited the only blue peak at 506 nm with an excitation wavelength at 253 nm.
机译:在表面活性剂聚乙二醇20000(PEG-20000)存在下,通过简便的水热方法可控制地合成了不同的钨酸锌(ZnWO4)纳米结构。在合成过程中,廉价和简单的无机盐被用作前体。 ZnWO4纳米/微结构的形状和大小可以通过表面活性剂的用量,反应体系的pH值和其他水热参数来很好地控制。除了ZnWO4纳米/微结构的结构和形态表征外,还分别通过粉末X射线衍射图和荧光分光光度计研究了典型样品的组成和光致发光(PL)特性。结果表明,所有形态不同的ZnWO4产物在506 nm处只有一个蓝峰,在253 nm处有一个激发波长。

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