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Synthesis of polyurethane using soybean oil based polyol and characterization of their coating properties

机译:大豆油基多元醇合成聚氨酯及其涂层性能表征

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Polymeric coatings based on renewable sources such as soybean oil is very attractive due to its low cost and biodegradable properties. The modification of two different polyols from soybean oil had been done in lab scale for polyurethane (PU) synthesis application. By reacting the modified polyol with Isophorone diisocyanate (IPDI) adduct, where different ratios of NCO/OH were used, polyurethane of various composition had been obtained. The samples of polyols and polyurethane obtained were characterized by FTIR spectroscopy. Types of Polyols prepared with various ratio of NCO/OH in each type of modification had been studied for coating properties (hardness, tensile and adhesion strength onto wood substrate). The result showed that the hardness and tensile strength of polyurethane is dependent on the ratio of NCO/OH.
机译:由于其低成本和可生物降解的特性,基于可再生资源(例如大豆油)的聚合物涂料非常有吸引力。已经从实验室规模对大豆油中的两种不同多元醇进行了改性,以用于聚氨酯(PU)合成应用。通过使改性多元醇与异佛尔酮二异氰酸酯(IPDI)加合物反应,其中使用了不同的NCO / OH比例,从而获得了各种组成的聚氨酯。通过FTIR光谱表征获得的多元醇和聚氨酯的样品。已经研究了在每种类型的改性剂中以不同比例的NCO / OH制备的多元醇的涂层性能(硬度,拉伸强度和在木材基材上的粘合强度)。结果表明,聚氨酯的硬度和拉伸强度取决于NCO / OH的比例。

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