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High Molecular Weight Copolymer Alkaline Fuel Cell Membrane via Miniemulsion Polymerization

机译:细乳液聚合的高分子量共聚物碱性燃料电池膜

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Proton exchange membrane fuel cells (PEMFC) have been largely investigated due to its possibility to be used commercially as the new generation power source. However, the high cost of PEMFC electrolyte membrane and catalysts as well as some technical issues like high dependency on water and limited temperature endurance (1) made this mission dimmed. Many scientists recently has turned to alkaline fuel cell (AFC) and tried to develop a solid anion exchange membrane (AEM) electrolyte that can be applied in AFC (2, 3, 4). However, the performances of those AFC are still barely satisfactory. Conductivity and mechanical property of AEM are two major challenges that impede the ultimate performances. The best conductivity of current AEM is still one order of magnitude lower than that of Nafion® (5), which exhibits higher ohmic loss in the performance polarization curve. Another issue is the mechanical property.
机译:由于质子交换膜燃料电池(PEMFC)有可能被商业用作新一代电源,因此已经进行了广泛的研究。但是,PEMFC电解质膜和催化剂的高成本以及诸如对水的高度依赖和有限的温度承受力(1)等一些技术问题使这项任务变得模糊了。最近,许多科学家转向碱性燃料电池(AFC),并试图开发可用于AFC的固体阴离子交换膜(AEM)电解质(2、3、4)。然而,那些亚足联的表现仍然勉强令人满意。 AEM的电导率和机械性能是阻碍最终性能的两个主要挑战。电流AEM的最佳电导率仍比Nafion®(5)的电导率低一个数量级,后者在性能极化曲线中表现出更高的欧姆损耗。另一个问题是机械性能。

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