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THERMAL CONDUCTIVITY OF NANO-POROUS BISMUTH ANTIMONY TELLURIDE

机译:纳米多孔铋锑碲化物的热导率

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Bismuth antimony telluride (Bi_(0.4)Te_(3.0)Sb_(1.6)) nano-porous thin films have been prepared and measured their thermal conductivities. The thin films exhibit an average grain size of 50 nm and random crystal orientation. The cross-plane thermal conductivity is measured by a differential 3ω method at temperature range from 100 to 300 K, and the determined thermal conductivities are from 0.09 to 0.18 W/(mK). As compared with bulk alloys at the same atomic composition, the nano-porous thin films exhibit an eightfold reduction in the thermal conductivity. For more detail analysis, the reduction of the thermal conductivity is examined by a simplified phonon gas model on a single crystal of bulk Bi_2Te_3. The analytical model fairly agreed with the experimental results, and thus we consider that the thermal conductivity is reduced by the strong phonon scattering at the nano-pores.
机译:制备了碲化铋锑(Bi_(0.4)Te_(3.0)Sb_(1.6))纳米多孔薄膜并测量了其热导率。薄膜表现出50nm的平均晶粒尺寸和无规的晶体取向。通过微分3ω法在100至300K的温度范围内测量横断面热导率,并且所确定的热导率是0.09至0.18W /(mK)。与相同原子组成的块状合金相比,纳米多孔薄膜的导热系数降低了八倍。为了进行更详细的分析,通过简化的声子气体模型在块体Bi_2Te_3的单晶上检查了导热系数的降低。该分析模型与实验结果完全吻合,因此我们认为通过纳米孔处的强声子散射降低了导热率。

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