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Numerical Simulation of Supercritical Water Oxidation with a Transpiring Wall Reactor

机译:透壁反应器对超临界水氧化的数值模拟

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Transpiring wall reactor is a promising engineering solution to corrosion and salt precipitation for the technology of supercritical water oxidation. Characteristics of flow conditions and species concentrations in the reactor and around the transpiring wall are hardly accessible to measurements. So a computational fluid dynamic model of the transpiring wall reactor was developed. The influence of different operating parameters on the temperature distribution and species distribution, especially the temperature near the transpiring wall, were investigated. Feed mass flow, feed flow temperature and ethanol concentration has a strong influence on the temperature of reactor. Higher feed mass flow, feed flow temperature and ethanol concentration are beneficial to the destruction of ethanol, but it reduces the protection of upper transpiring wall. The optimum feed flow for the reactor is between 0.002 and 0.003kg/s at 380 °C, Transpiration intensity has minimal influence on the temperature, but lower transpiring flow temperature is beneficial to protection of the porous wall. Upper branch transpiring water of 300 0;C provides a subcritical protective film to prevent corrosion and salt precipitation.
机译:透壁反应器是超临界水氧化技术解决腐蚀和盐分沉淀的有前途的工程解决方案。测量中难以接近反应器中和蒸发壁周围的流动条件和物质浓度的特征。因此,建立了透热壁反应器的计算流体动力学模型。研究了不同操作参数对温度分布和物种分布的影响,特别是对蒸腾壁附近温度的影响。进料质量流量,进料流量温度和乙醇浓度对反应器温度有强烈影响。较高的进料质量流量,进料温度和乙醇浓度有利于乙醇的破坏,但降低了对上蒸腾壁的保护。反应器的最佳进料流量在380°C时在0.002至0.003kg / s之间,蒸腾强度对温度的影响最小,但较低的流通温度有利于保护多孔壁。 300 0; C的上支流汗水可提供亚临界保护膜,以防止腐蚀和盐分沉淀。

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