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Silicone rubber compositions with yttrium-doped ceramics for outdoor insulation

机译:用于户外隔热的掺有钇陶瓷的硅橡胶组合物

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In this work, the effect of barium titanate (BaTiO3) powder doped with yttrium (Y) when used as filler in silicone rubber was studied. Y3+ ions replace the Ba2+ ions in the BaTiO3 crystal lattice in a concentration of 0.4 at.% using a thermal treatment at 1300°C during 1 hour. The dielectric constant of this ceramic powder (K=692) is almost five times bigger as compared to pure BaTiO3 (K=154). This powder was incorporated to the silicone matrix in a 40 vol.% obtaining a good dispersion but the dielectric constant of the composite is not greatly increased (K=10.61); however, its electrical conductivity is decreased compared to a pure BaTiO3 composite prepared with the same conditions. Electric field simulations were performed considering the properties of the obtained composites at power frequency and under impulse voltage for a bushing and a long rod insulator.
机译:在这项工作中,研究了掺钇(Y)的钛酸钡(BaTiO 3 )粉末在硅橡胶中用作填料的效果。 Y 3 + 离子通过在110℃下进行热处理,以0.4 at。%的浓度代替BaTiO 3 晶格中的Ba 2 + 离子。在1小时内达到1300°C。该陶瓷粉末的介电常数(K = 692)几乎是纯BaTiO 3 (K = 154)的五倍。将该粉末以40体积%掺入硅氧烷基体中,获得良好的分散性,但复合材料的介电常数并未大大提高(K = 10.61)。然而,与在相同条件下制备的纯BaTiO 3 复合材料相比,其电导率降低了。考虑套管和长杆绝缘子在电源频率和脉冲电压下获得的复合材料的性能,进行了电场模拟。

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