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Almond shell based chemically activated carbons for toluene adsorption

机译:杏仁壳基化学活性炭吸附甲苯

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Volatile organic compounds (VOCs) are atmospheric pollutants coming from the use of solvents in the industry and the storage, distribution and use of fossil fuels. VOCs have direct effect on human health. Moreover, they participate in reactions in the atmosphere with other pollutants contributing to the formation of tropospheric ozone calling them ozone precursors. Toluene is a VOC commonly used as solvent in the industry. Activated carbons have the ability to adsorb it and in a further step, recover it by desorption accomplishing one hand legislation concerning VOC emissions and on the other hand recovering a valuable solvent to be reused in the industry process. In this work, activated carbons have been obtained from the chemical activation with phosphoric acid of almond shells at different impregnation ratios and temperature and time of carbonization. The activated carbons have been extensively characterized by different techniques (TG-DTA, FTIR, TPD, N_2 physisorption). The adsorption capacity of toluene of the carbons obtained was tested, as well as the behaviour of carbons along several cycles of adsorption desorption.
机译:挥发性有机化合物(VOC)是大气污染物,源于工业中溶剂的使用以及化石燃料的存储,分配和使用。 VOC对人类健康有直接影响。此外,它们与其他污染物一起参与大气中的反应,从而导致形成对流层臭氧,称其为臭氧前体。甲苯是工业上通常用作溶剂的VOC。活性炭具有吸附它的能力,并在下一步中通过解吸来回收它,一方面完成了有关VOC排放的法规,另一方面又回收了有价值的溶剂,可在工业过程中重复使用。在这项工作中,已经从杏仁壳的磷酸在不同的浸渍率,碳化的温度和时间的化学活化作用中获得了活性炭。活性炭已通过不同技术(TG-DTA,FTIR,TPD,N_2物理吸附)进行了广泛表征。测试了甲苯对所得碳的吸附能力,以及碳在几个吸附解吸循环中的行为。

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